Les of FhbF. graminearumRachis and spikelets; Inoculated at anthesis; Harvested at haiLCESILTQOrbitrapRachisesSpikelets:Fatty acids; Phenylpropanoids; TerpenoidsInt. J. Mol. SciTable . Cont.Pathosystem Plant Black barley. linessusceptible; resistant Yellow barley. lines susceptible; resistant Pathogen Element of the Plant; Stage of Inoculation ab; Harvesting a Spikelets; Inoculation at GS (anthesis to early milk stage); Harvested at hai Technology Database Putatively Identified metabolites Linked to FHB Resistance Major Chemical GroupsReferenceF. graminearumLCESILTQOrbitrapNot cited Identification by spiking with requirements PlanyCyc; METLIN; KNApSAcK; KEGGAmino acids; Carbohydrates; Fatty acids; Phenylpropanoids Alkaloids; Fatty acids; Acetylene-linker-Val-Cit-PABC-MMAE site Hydroxycinnamic acids; Phenylpropanoids; TerpenoidsBarley. linessusceptible; resistantF. graminearumSpikelets; Inoculation at anthesis; Harvested at haiLCESILTQOrbitrapBarley. varietiesAktiv; Gladys; Henrike; Lilly; Radegast; Sebastian; Signora; Sladar; Tolar Wheat cultivarssusceptible (Roblin); resistant (Sumai)F. culmorumNA; Inoculated in the beginning of heading Harvested at dai Rachis Inoculated GS (anthesis) Harvested at daiUHPLCQTOFMSPlanyCyc; METLIN; MassBankFatty acids; PhenylpropanoidsF. graminearumLCESILTQOrbitrap,METLIN; MassBank; MSTAmino acids; Carbohydrates; Phenylpropanoids; Terpenoidsahaihours following inoculation, daidays following inoculation, NAnot accessible; b GSGrowth Stage on the Zadocks scale .Int. J. Mol. Sci. ,Figure . Chemical diversity of metabolites which have been pinpointed for their prospective contribution to FHB resistance GSK2838232 web through the achievement of metabolomic research and have already been putatively identified Chemical Groups Potentially Involved in Chemical Defense against DON Making Fusarium Species Metabolites Derived from the Phenylpropanoid Pathway . Flavonoid Phenylpropanoids As illustrated on Figure , metabolites putatively related using the phenylpropanoid pathway are frequently reported for their prospective contribution to chemical defense against F. graminearum plus the production of DON. Additional than diverse PubMed ID:https://www.ncbi.nlm.nih.gov/pubmed/17109846 compounds have been highlighted through the achievement on the metabolomic studies gathered in Table and were putatively assigned to phenylpropanoid compounds. Plant phenylpropanoids encompass many classes of structurally diverse compounds synthesized from the amino acid phenylalanine, including flavonoids including anthocyanins, flavones, flavonols, flavanones, flavanols, isoflavones, isoflavanones, isoflavonols and chalcones, and nonflavonoids which include phenolic acids, phenolic alcohols, phenolic aldehydes, stilbenes, lignans and coumarins (Tables and). Amongst the metabolites putatively assigned to phenylpropanoids, a lot more than had been supposed to belong for the flavonoid class (Figure). Many information support the involvement of phenylpropanoid compounds in plant resistance to fungal pathogens , which mostly results from their antibiotic properties, their crucial role as plant defense mediators and their participation to cell wall lignification. Some phenylpropanoids are created constitutively 
and function as preformed antibiotics in nonhost resistance to pathogens; they are created as phytoanticipins. Others, which biosynthesis is induced in response for the pathogen ingress, participate to active plant defense mechanisms and can be classified as phytoalexins . As indicated in Table , practically putative flavonoids that could contribute for the chemical arsenal of wheat and barley aga.Les of FhbF. graminearumRachis and spikelets; Inoculated at anthesis; Harvested at haiLCESILTQOrbitrapRachisesSpikelets:Fatty acids; Phenylpropanoids; TerpenoidsInt. J. Mol. SciTable . Cont.Pathosystem Plant Black barley. linessusceptible; resistant Yellow barley. lines susceptible; resistant Pathogen Portion from the Plant; Stage of Inoculation ab; Harvesting a Spikelets; Inoculation at GS (anthesis to early milk stage); Harvested at hai Technologies Database Putatively Identified metabolites Linked to FHB Resistance Key Chemical GroupsReferenceF. graminearumLCESILTQOrbitrapNot cited Identification by spiking with standards PlanyCyc; METLIN; KNApSAcK; KEGGAmino acids; Carbohydrates; Fatty acids; Phenylpropanoids Alkaloids; Fatty acids; Hydroxycinnamic acids; Phenylpropanoids; TerpenoidsBarley. linessusceptible; resistantF. graminearumSpikelets; Inoculation at anthesis; Harvested at haiLCESILTQOrbitrapBarley. varietiesAktiv; Gladys; Henrike; Lilly; Radegast; Sebastian; Signora; Sladar; Tolar Wheat cultivarssusceptible (Roblin); resistant (Sumai)F. culmorumNA; Inoculated at the starting of heading Harvested at dai Rachis Inoculated GS (anthesis) Harvested at daiUHPLCQTOFMSPlanyCyc; METLIN; MassBankFatty acids; PhenylpropanoidsF. graminearumLCESILTQOrbitrap,METLIN; MassBank; MSTAmino acids; Carbohydrates; Phenylpropanoids; Terpenoidsahaihours right after inoculation, daidays following inoculation, NAnot offered; b GSGrowth Stage around the Zadocks scale .Int. J. Mol. Sci. ,Figure . Chemical diversity of metabolites that have been pinpointed for their possible contribution to FHB resistance through the achievement of metabolomic studies and have already been putatively identified Chemical Groups Potentially Involved in Chemical Defense against DON Making Fusarium 
Species Metabolites Derived from the Phenylpropanoid Pathway . Flavonoid Phenylpropanoids As illustrated on Figure , metabolites putatively connected with the phenylpropanoid pathway are often reported for their potential contribution to chemical defense against F. graminearum as well as the production of DON. Far more than distinct PubMed ID:https://www.ncbi.nlm.nih.gov/pubmed/17109846 compounds happen to be highlighted via the achievement on the metabolomic research gathered in Table and were putatively assigned to phenylpropanoid compounds. Plant phenylpropanoids encompass various classes of structurally diverse compounds synthesized in the amino acid phenylalanine, including flavonoids which include anthocyanins, flavones, flavonols, flavanones, flavanols, isoflavones, isoflavanones, isoflavonols and chalcones, and nonflavonoids such as phenolic acids, phenolic alcohols, phenolic aldehydes, stilbenes, lignans and coumarins (Tables and). Among the metabolites putatively assigned to phenylpropanoids, far more than have been supposed to belong for the flavonoid class (Figure). Numerous information support the involvement of phenylpropanoid compounds in plant resistance to fungal pathogens , which mostly results from their antibiotic properties, their crucial part as plant defense mediators and their participation to cell wall lignification. Some phenylpropanoids are produced constitutively and function as preformed antibiotics in nonhost resistance to pathogens; they’re designed as phytoanticipins. Other folks, which biosynthesis is induced in response for the pathogen ingress, participate to active plant defense mechanisms and may be classified as phytoalexins . As indicated in Table , practically putative flavonoids that could contribute for the chemical arsenal of wheat and barley aga.